LFNano™

LOW-FOULING NANOFILTRATION (LFNano™)

LFNano™ DESCRIPTION

APPLICATION BULLETIN: RO PRE-TREAT

APPLICATION BULLETIN: WASTEWATER TREATMENT

NANOFILTRATION MEMBRANE

Membranes are divided into two categories, filtration membranes and osmotic membranes. Filtration membranes largely do not remove dissolved contaminants while osmotic ones do.  Osmotic membranes also remove larger suspended particles than filtration membranes do.

While the low-pressure filtration membranes have experienced tremendous growth over the past decade, they lack the ability to remove natural organic matter (NOM).  Most every water treatment application requires the removal of (or neutralizing of) NOM.  Conversely, very few water treatment applications require the removal of dissolved solids.

The dividing point (see chart below) between what virtually all water treatment applications require and what very few applications require (desalting) falls on the nanofiltration (NF) membrane (see chart below). Rather than combine processes of low pressure membranes and disinfectant technologies, DXV has developed an inexpensive NF process to accomplish in one step what now can take several steps with traditional treatment processes.

                       

Membrane water treatment has a long history for specialty uses such as ultra-pure water and desalination, but less history with drinking water or wastewater treatment.  Membrane filtration using low pressure, large pore membranes such as microfiltration (MF) and ultrafiltration (UF) is becoming more common in water and wastewater treatment applications. However, these systems are complex due to the frequent fouling of the membranes. The fouling necessitates complex and expensive cleaning and backwash systems.  These cleaning systems require chemicals and automated backwashing occurring as frequently as every 15 minutes.  

Tighter osmotic membranes that remove dissolved constituents are also susceptible to fouling.  Reverse osmosis (RO) and nanofiltration (NF) membranes require extensive pre-treatment, generally by the MF or UF membranes in order to achieve acceptable cleaning cycles.  Such two-stage processes are too costly for many water treatment applications.

DXV has developed an NF membrane system that does not require pre-treatment or process chemicals, with cleaning intervals measured in months and years rather than minutes and weeks.  The DXV low-fouling nanofiltration system (“LFNano™”) consists of a unique membrane system that is designed to avoid particulate fouling, biofouling and scaling.  After eight (8) months of operation the first prototype test required just five (5) psi of additional pressure to maintain starting flux.

The system’s ability to avoid fouling makes it ideal for challenging water sources.  The dirtier the water the more value added by the LFNano™ making even wastewater treatment more affordable than current treatment methods.

SIMPLE TREATMENT

Water and wastewater treatment is complex because of the many steps and consumables required.  Filtration media often foul and require backwashing or cleaning and disinfection technologies often leave compounds with unknown long term effects in the water.   DXV’s treatment system is a one-step system that creates extremely high quality effluent by removing contaminants.  Because of its configuration the LFNano™ operates at vastly different operating parameters than traditional osmotic membranes. The system uses low flux and low pressure to minimize fouling and reduce cost.

NO PROCESS CHEMICALS

Chemicals are often used in water treatment for various reasons including biocide and anti scaling.  DXV’s treatment system requires no chemicals.  The lack of chemicals allows lower cost installations not requiring expensive storage, injection and containment systems.

leo vdl

LOW MAINTENANCE

Pilots of the LFNano™ system have shown over eight months of continuous operation with little pressure creep while treating wastewater effluent (notoriously high in foulants).  This data show that, depending on the water source, we can expect several months to years between active membrane cleanings.  This compares to typical low pressure membranes backwashing every 15 to 45 minutes and several weeks on high pressure membranes that are preceded by vigorous pretreatment (including low pressure membranes).

low maintenance

LOW ENERGY

The unique membrane cartridge in the LFNano™ membrane system allows for very low pressure operation.  This low resistance membrane element allows a high cross flow velocity with little energy consumption.  In addition, the use of low rejection NF membranes at relatively low flux rates keeps the operating pressure very low. Most applications will be optimized at between 15 and 40 psi.

low energy

 

 

 

 

 

APPLICATIONS

The LFNano™ can be used for a myriad of water treatment needs as it is extremely flexible relative to the source water quality.  This section briefly discusses a few of the more broad applications that will be greatly improved by the use of the system.

Wastewater – NF membranes have not been considered for wastewater treatment as their current embodiment requires significant pre-treatment that is expensive in wastewater.  NF membranes can reject organics to a very high degree, making them suitable for wstewater treatment without a biological digestion process.  Depending on the water source additional removal of nutrients might be required, but this is a simple additional process when the water is so clean.

Membranes can be used to treat about any water, but the cost effectiveness is often at issue.  NF membrane can be used on wastewater today but at tremendous expense. The LFNano™ simplifies membrane treatment making it competitive with many existing technologies.

wastewater

Surface water – Surface water treatment can be improved greatly with an LFNano™ system as it removes far more contaminants than MF or UF systems and does so without any chemical addition to the feedwater as is common in other treatment systems today.  With no chemical addition, the system can be operated at low recovery rates leaving a chemical-free concentrate stream.  Also, at low recovery rates, even natural contaminants do not concentrate much. In such low recovery cases, the concentrate can be returned to the environment with no negative repercussions. Alternatively, a high recovery process is also possible without an increase in the osmotic pressure requirement as is common with RO membranes.

surface h2o

Pre-treatment – RO systems today require significant pre-treatment, generally with other membranes.  Traditional membrane pre-treatment uses low pressure membranes that do not remove much of the dissolved organics and scale forming ions.  It is these dissolved constituents that cause the fouling of the downstream RO or NF membranes.  By using the LFNano™ as pre-treatment, the feedwater to the RO stage will be void of the dissolved organics and most of the multi-valent ions that cause scaling.  The downstream membranes will then require little maintenance which will extend their useful life.

RO

Emergency treatment – Many mobile treatment systems are constructed to provide clean water in emergency situations such as after a natural disaster or in military operations.  These mobile systems do not have the benefit of a thorough feed water analysis before they are needed so many contingencies must be accomodated.  This requires the transport of multiple treatment chemicals. The LFNano™ can handle a wide variety of feed waters with the same chemical-free process.  This makes it ideal for such contingency operations.

emergency

ENVIRONMENTAL BENEFITS

Chemicals are largely eliminated from the water treatment process with the LFNano™.  The production and use of chemicals is fraught with environmental impacts.  Further, the unintended consequences of byproducts created in our water by modern disinfection techniques will not be completely known for decades.  The LFNano™ system removes contaminants rather than chemically altering them or inactivating them (bacteria or viruses).

Discharge – The discharge of treated wastewater into the environment has direct impacts on the water to which it is discharged.  The organics in the treated wastewater alter the environment.  The LFNano™ system removes these constituents so that the effluent can be safely disposed of while leaving the environment much closer to its natural state.

discharge

Reuse – The reuse of reclaimed wastewater offsets withdrawals from the environment and their associated impacts.  Reuse with the LFNano™ greatly improves the efficiency of the entire water reclamation process by virtue of a one-step, chemical free method of producing NF quality effluent that can be further processed (RO/NF spiral and/or disinfection) for potable reuse.  Wastewater reuse is far less energy intensive than traditional seawater desalination thus potentially offsetting the need for energy intensive desalination projects.

reuse

FOOTPRINT

The LFNano™ membrane elements and vessels will occupy less space than a comparable MF or UF system. MF/UF backwash and cleaning systems require frequent backwash which requires a complex series of automated valves and controls.  The required chemical storage and injection equipment also occupies significant space.  When the LFNano™ is in pre-treatment mode ahead of an RO stage, the RO will be operated much more efficiently and not require maintenance shutdowns.  Therefore less RO capacity is required to maintain a consistent throughput.  The DXV LFNano™ system will have a more compact footprint in most all applications despite a lower packing density.

WATER TREATMENT HISTORY

Worldwide, membrane water treatment is in its infancy but a variety of factors are contributing to its growth.  The history of water treatment is long and is in a period of transition with the membrane revolution taking hold. 

Man has been using water that has been purified the same way for millennia. As an example, the figure below shows how the Floridian Aquifer is replenished by the infiltration of surface water. This water is filtered by the soil as it percolates into the massive underground storage aquifers, naturally cleaning the water. In comparison, when we use a surface water source directly, it must be cleaned by other methods in order to ensure it is safe.                                                             

Aquifer

People have developed systems that mimic the way the Earth cleans water in aquifers by filtering the water through a bed of sand or other porous substrate. The current version of this method, Rapid Sand Filtration (RSF), is the way we treat most all surface water sources and even tertiary treated wastewater. This method of treatment is land and maintenance intensive as the media bed is frequently in need of backwashing. In addition, it does not provide a firm physical barrier and can be easily penetrated by contaminants if not operated properly.

In the 1980’s a few firms began to develop low pressure microfiltration (MF) and later ultrafiltration (UF) membrane systems that can treat water to a much higher quality than RSF. These systems were initially expensive and complex, but they provided a physical barrier to contaminants up to the 0.1 to 1 microns (millionths of a meter, 10-6) range while sand filtration only effectively removed particles down to about 100 microns in size. These systems were adopted on a limited basis only as the incremental safety improvement they offered did not justify the significant complexity and expense.

Microfiltration and ultrafiltration membranes offered better removal of bacteria (MF) and even viruses (UF). When an outbreak of Cryptosporidium illness in Milwaukee in 1993 caused a reported 54 deaths, many started to look into more secure water treatment methods than traditional sand filtration. The concern caused by the Milwaukee outbreak created a demand for tighter filtration methods such as MF and UF membrane systems. As the cost of these systems came down, more applications became economical and membranes grew in usage. Currently MF and UF treatment are common in new installations, but still represent a small fraction of the installed treatment capacity in the United States.

This trend was highlighted by a leading MF/UF membrane supplier in their 2005 annual report which showed the pickup in the demand for their membrane systems as the cost of treatment came down over time. This leading low pressure membrane (MF/UF) supplier published the graph below in their 2005 annual report.

 

It is clear that the reduction in the cost of membrane treatment stimulated significant demand as the cost dropped by 80% in the four years from 1995 to 1999. Today MF and UF systems are used to treat drinking water, pre-treat RO feedwater, and treat wastewater in membrane bio-reactor (MBR) systems. However, their frequent fouling and high maintenance cost still limit their adoption. In addition, for pre-treatment applications ahead of high pressure membranes, they do not remove many of the organic and scale producing foulants resulting in frequent cleaning of the RO membranes.